55 citations · 356 across the 23 of their papers we have counts for
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Electrosorption-induced deformation of a porous electrode with non-convex pore geometry in electrolyte solutions: a theoretical study
A. L. Kolesnikov, D. A. Mazur, Yu. A. Budkov
Porous carbon is well known as a good candidate for the development of electrochemical double-layer capacitors. Predominantly, many conventional carbons are microporous and often w…
Modified Poisson-Boltzmann equations and macroscopic forces in inhomogeneous ionic fluids
Yu. A. Budkov, A. L. Kolesnikov
We propose a field-theoretical approach based on the thermodynamic perturbation theory and within it derive a grand thermodynamic potential of the inhomogeneous ionic fluid as a fu…
Electric double layer theory for room temperature ionic liquids on charged electrodes: milestones and prospects
Yury A. Budkov, Andrei L. Kolesnikov
In this review, we shortly summarize the basic theoretical milestones achieved in the mean-field theory of room temperature ionic liquids (RTILs) on charged electrodes since the pu…
Electrochemistry meets polymer physics: polymerized ionic liquids on an electrified electrode
Yury A. Budkov, Nikolai N. Kalikin, Andrei L. Kolesnikov
Polymeric ionic liquids are emerging polyelectrolyte materials for modern electrochemical applications. In this paper, we propose a self-consistent field theory of the polymeric io…
Influence of fluid flows on electric double layers in evaporating colloidal sessile droplets
Semen V. Zavarzin, Andrei L. Kolesnikov, Yury A. Budkov +1
A model is developed for describing the transport of charged colloidal particles in an evaporating sessile droplet on the electrified metal substrate in the presence of a solvent f…
A crossover of the solid substances solubility in supercritical fluids: what is it in fact?
N. N. Kalikin, R. D. Oparin, A. L. Kolesnikov +2
We investigate a well-known phenomenon of the appearance of the crossover points, corresponding to the intersections of the solubility isotherms of the solid compound in supercriti…
On gyration radius distributions of star-like macromolecules
Yu. A. Budkov, A. L. Kolesnikov
Using the path integral approach, we obtain the characteristic functions of the gyration radius distributions for Gaussian star and Gaussian rosette macromolecules. We derive the a…
Two-component electrolyte solutions with dipolar cations on a charged electrode: Theory and computer simulations
Yu. A. Budkov, A. V. Sergeev, S. V. Zavarzin +1
The development of advanced electrochemical devices for energy conversion and storage requires fine tuning of electrode reactions, which can be accomplished by altering the electro…
Nonlocal density functional theory of water taking into account many-body dipole correlations: Binodal and surface tension of 'liquid-vapour' interface
Yu. A. Budkov, A. L. Kolesnikov
In this paper we formulate a nonlocal density functional theory of inhomogeneous water. We model a water molecule as a couple of oppositely charged sites. The negatively charged si…
Metal-Organic Framework Breathing in Electric Field: A Theoretical Study
Andrei L. Kolesnikov, Yury A. Budkov, Jens Möllmer +2
In this manuscript, we study the electrically induced breathing of Metal-Organic Framework (MOF) within a 2D lattice model. The Helmholtz free energy of the MOF in electric field c…
Statistical description of co-nonsolvency suppression at high pressures
Yu. A. Budkov, A. L. Kolesnikov
We present an application of Flory-type self-consistent field theory of the flexible polymer chain dissolved in the binary mixture of solvents to theoretical description of co-nons…
Polymer chain collapse induced by many-body dipole correlations
Yu. A. Budkov, N. N. Kalikin, A. L. Kolesnikov
We present a simple analytical theory of flexible polymer chain dissolved in a good solvent, carrying permanent freely oriented dipoles on the monomers. We take into account the di…
Polarizable polymer chain under external electric field: Effects of many-body electrostatic dipole correlations
Yu. A. Budkov, A. L. Kolesnikov
We present a new simple self-consistent field theory of the polarizable flexible polymer chain under the external constant electric field with account for the many-body electrostat…
On a new application of the path integrals in polymer statistical physics
Yu. A. Budkov, A. L. Kolesnikov
We propose a new approach based on the path integral formalism to the calculation of the probability distribution functions of quadratic quantities of the Gaussian polymer chain in…
A statistical theory of coil-to-globule-to-coil transition of a polymer chain in the mixture of good solvents
Yu. A. Budkov, A. L. Kolesnikov, N. N. Kalikin +1
We present an off-lattice statistical model of a single polymer chain in mixed solvent media. Taking into account a polymer conformational entropy, renormalization of solvent compo…
On the theory of electric double layer with explicit account of a polarizable co-solvent
Yu. A. Budkov, A. L. Kolesnikov, M. G. Kiselev
We present a continuation of our theoretical research into the influence of co-solvent polarizability on a differential capacitance of the electric double layer [EPL 111, 28002 (20…
Polarizable polymer chain under external electric field in a dilute polymer solution
Yu. A. Budkov, A. L. Kolesnikov, M. G. Kiselev
We study the conformational behavior of polarizable polymer chain under an external homogeneous electric field within the Flory type self-consistent field theory. We consider the i…
A modified Poisson-Boltzmann theory: Effects of co-solvent polarizability
Y. A. Budkov, A. L. Kolesnikov, M. G. Kiselev
In this paper within a field-theoretical approach taking into account explicitly a co-solvent with a nonzero dipole and a polarizability tensor, we derive a modified Poisson-Boltzm…
A new equation of state of a flexible-chain polyelectrolyte solution: Phase equilibria and osmotic pressure in the salt-free case
Yu. A. Budkov, A. L. Kolesnikov, N. Georgi +2
We develop a first-principle equation of state of salt-free polyelectrolyte solution in the limit of infinitely long flexible polymer chains in the framework of a field-theoretical…