On a new application of the path integrals in polymer statistical physics
arXiv:1607.07017 · doi:10.1088/1742-5468/2016/10/103211
Abstract
We propose a new approach based on the path integral formalism to the calculation of the probability distribution functions of quadratic quantities of the Gaussian polymer chain in d-dimensional space, such as the radius of gyration and potential energy in the parabolic well. In both cases we obtain the exact relations for the characteristic function and cumulants. Using the standard steepest-descent method, we evaluate the probability distribution functions in two limiting cases of the large and small values of corresponding variables.
arXiv commentThis manuscript has been accepted for publication in Journal of Statistical Mechanics: Theory and experiment
References in corpus (5)
- Chain Collapse and Counterion Condensation in Dilute Polyelectrolyte Solutions
- A Statistical Theory of cosolvent-induced coil-globule transitions in dilute polymer solution
- A flexible polymer chain in a critical solvent: Coil or globule?
- Polarizable polymer chain under external electric field in a dilute polymer solution
- The local phase transitions of the solvent in the neighborhood of a solvophobic polymer at high pressures
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