On the theory of electric double layer with explicit account of a polarizable co-solvent
arXiv:1602.04986 · doi:10.1063/1.4948634
Abstract
We present a continuation of our theoretical research into the influence of co-solvent polarizability on a differential capacitance of the electric double layer [EPL 111, 28002 (2015)]. We formulate a modified Poisson-Boltzmann theory, using the formalism of density functional approach on the level of local density approximation taking into account the electrostatic interactions of ions and co-solvent molecules as well as their excluded volume. We derive the modified Poisson-Boltzmann equation, considering the three-component symmetric lattice gas model as a reference system and minimizing the grand thermodynamic potential with respect to the electrostatic potential. We apply present modified Poisson-Boltzmann equation to the electric double layer theory.
References in corpus (4)
- Differential capacitance of the electric double layer: The interplay between ion finite size and dielectric decrement
- Surface Tension of Electrolyte Interfaces: Ionic Specificity within a Field-Theory Approach
- A modified Poisson-Boltzmann theory: Effects of co-solvent polarizability
- Dipolar correlations in structured solvents under nanoconfinement
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- Theory of electrolyte solutions in a slit charged pore: effects of structural interactions and specific adsorption of ions
- Nonlocal statistical field theory of dipolar particles forming chain-like clusters
- Electrochemistry meets polymer physics: polymerized ionic liquids on an electrified electrode
- Influence of asymmetric depletion of solvents on the electric double layer of charged objects in binary polar solvent mixture
- Comment on "Nonlocal statistical field theory of dipolar particles in electrolyte solutions" by Y.A. Budkov