55 citations
Counting papers with at most 25 authors, so collaboration author lists do not stand in for the people here.
- National Research University Higher School of EconomicsRU22 papers
- Institut für Nichtklassische ChemieDE15 papers
- Leipzig UniversityDE8 papers
- Moscow State Institute of Electronics and MathematicsRU6 papers
- Ivanovo State UniversityRU5 papers
- Max Planck Institute for Mathematics in the SciencesDE4 papers
- Lomonosov Moscow State UniversityRU3 papers
- Max Planck Institute for MathematicsDE2 papers
- Russian Academy of SciencesRU2 papers
- University of LeicesterGB2 papers
- Institute of Theoretical and Experimental BiophysicsRU1 paper
- Italian Institute of TechnologyIT1 paper
25 papers
Theory of electrolyte solutions in a slit charged pore: effects of structural interactions and specific adsorption of ions
Victoria A. Vasileva, Daria A. Mazur, Yury A. Budkov
In this paper, we present a continuation of our research on modeling electrolyte solutions within charged slit pores. We make use of the model developed by Blossey et al., which ta…
Noether's second theorem and covariant field theory of mechanical stresses in inhomogeneous ionic liquids
P. E. Brandyshev, Yu. A. Budkov
In this paper, we present a covariant approach that utilizes Noether's second theorem to derive a symmetric stress tensor from the grand thermodynamic potential functional. We focu…
Macroscopic forces in inhomogeneous polyelectrolyte solutions
Yury Budkov, Nikolai Kalikin
In this paper, we present a self-consistent field theory of macroscopic forces in spatially inhomogeneous flexible chain polyelectrolyte solutions. We derive an analytical expressi…
Electrosorption-induced deformation of a porous electrode with non-convex pore geometry in electrolyte solutions: a theoretical study
A. L. Kolesnikov, D. A. Mazur, Yu. A. Budkov
Porous carbon is well known as a good candidate for the development of electrochemical double-layer capacitors. Predominantly, many conventional carbons are microporous and often w…
Modified Poisson-Boltzmann equations and macroscopic forces in inhomogeneous ionic fluids
Yu. A. Budkov, A. L. Kolesnikov
We propose a field-theoretical approach based on the thermodynamic perturbation theory and within it derive a grand thermodynamic potential of the inhomogeneous ionic fluid as a fu…
Electrochemistry meets polymer physics: polymerized ionic liquids on an electrified electrode
Yury A. Budkov, Nikolai N. Kalikin, Andrei L. Kolesnikov
Polymeric ionic liquids are emerging polyelectrolyte materials for modern electrochemical applications. In this paper, we propose a self-consistent field theory of the polymeric io…
A crossover of the solid substances solubility in supercritical fluids: what is it in fact?
N. N. Kalikin, R. D. Oparin, A. L. Kolesnikov +2
We investigate a well-known phenomenon of the appearance of the crossover points, corresponding to the intersections of the solubility isotherms of the solid compound in supercriti…
On gyration radius distributions of star-like macromolecules
Yu. A. Budkov, A. L. Kolesnikov
Using the path integral approach, we obtain the characteristic functions of the gyration radius distributions for Gaussian star and Gaussian rosette macromolecules. We derive the a…
Two-component electrolyte solutions with dipolar cations on a charged electrode: Theory and computer simulations
Yu. A. Budkov, A. V. Sergeev, S. V. Zavarzin +1
The development of advanced electrochemical devices for energy conversion and storage requires fine tuning of electrode reactions, which can be accomplished by altering the electro…
Statistical field theory of ion-molecular solutions
Yu. A. Budkov
In this article, I summarize my theoretical developments in the statistical field theory of salt solutions of zwitterionic and multipolar molecules. Based on the Hubbard-Stratonovi…
Molecular fields and statistical field theory of fluids. Application to interface phenomena
Nikolai V. Brilliantov, J. Miguel Rubi, Yury A. Budkov
Using the integral transformation, the field-theoretical Hamiltonian of the statistical field theory of fluids is obtained, along with the microscopic expressions for the coefficie…
Nonlocal density functional theory of water taking into account many-body dipole correlations: Binodal and surface tension of 'liquid-vapour' interface
Yu. A. Budkov, A. L. Kolesnikov
In this paper we formulate a nonlocal density functional theory of inhomogeneous water. We model a water molecule as a couple of oppositely charged sites. The negatively charged si…
High-pressure NMR spectroscopy in studies of the conformational composition of small molecules of ibuprofen in supercritical carbon dioxide
Ilya Khodov, Alexey Dyshin, Sergey Efimov +2
An experimental approach in conducting NMR measurements at supercritical parameters of state is discussed. A novel design of the high-pressure NMR cell was developed which allowed…
Metal-Organic Framework Breathing in Electric Field: A Theoretical Study
Andrei L. Kolesnikov, Yury A. Budkov, Jens Möllmer +2
In this manuscript, we study the electrically induced breathing of Metal-Organic Framework (MOF) within a 2D lattice model. The Helmholtz free energy of the MOF in electric field c…
Nonlocal statistical field theory of dipolar particles forming chain-like clusters
Yu. A. Budkov
We present a nonlocal statistical field theory of a diluted solution of dipolar particles which are capable of forming chain-like clusters in accordance with the 'head-to-tail' mec…
Nonlocal statistical field theory of dipolar particles in electrolyte solutions
Yu. A. Budkov
We present a nonlocal statistical field theory of a dilute electrolyte solution with small additive of dipolar particles. We postulate that every dipolar particle is associated wit…
Statistical theory of fluids with a complex electric structure: Application to solutions of soft-core dipolar particles
Yu. A. Budkov
Based on the thermodynamic perturbation theory (TPT) and the Random phase approximation (RPA), we present a statistical theory of solutions of electrically neutral soft molecules,…
On the theory of electric double layer with explicit account of a polarizable co-solvent
Yu. A. Budkov, A. L. Kolesnikov, M. G. Kiselev
We present a continuation of our theoretical research into the influence of co-solvent polarizability on a differential capacitance of the electric double layer [EPL 111, 28002 (20…
Polarizable polymer chain under external electric field in a dilute polymer solution
Yu. A. Budkov, A. L. Kolesnikov, M. G. Kiselev
We study the conformational behavior of polarizable polymer chain under an external homogeneous electric field within the Flory type self-consistent field theory. We consider the i…
A modified Poisson-Boltzmann theory: Effects of co-solvent polarizability
Y. A. Budkov, A. L. Kolesnikov, M. G. Kiselev
In this paper within a field-theoretical approach taking into account explicitly a co-solvent with a nonzero dipole and a polarizability tensor, we derive a modified Poisson-Boltzm…
A new equation of state of a flexible-chain polyelectrolyte solution: Phase equilibria and osmotic pressure in the salt-free case
Yu. A. Budkov, A. L. Kolesnikov, N. Georgi +2
We develop a first-principle equation of state of salt-free polyelectrolyte solution in the limit of infinitely long flexible polymer chains in the framework of a field-theoretical…
Field-regulated force by grafted polyelectrolytes
Christian Seidel, Yury A. Budkov, Nikolay V. Brilliantov
Generation of mechanical force regulated by external electric field is studied both theoretically and by molecular dynamics (MD) simulations. The force arises in deformable bodies…
A Statistical Theory of cosolvent-induced coil-globule transitions in dilute polymer solution
Yu. A. Budkov, A. L. Kolesnikov, N. Georgi +1
We present a statistical model of a dilute polymer solution in good solvent in the presence of low-molecular weight cosolvent. We investigate the conformational changes of the poly…
The local phase transitions of the solvent in the neighborhood of a solvophobic polymer at high pressures
Yu. A. Budkov, I. I. Vyalov, A. L. Kolesnikov +3
We investigate local phase transitions of the solvent in the neighborhood of a solvophobic polymer chain which is induced by a change of the polymer-solvent repulsion and the solve…