activity
20152022
most citedPerformance Metrics for the Objective Assessment of Capacitive Deionization Systems

287 citations · 336 across the 10 of their papers we have counts for

collaborators

11 papers

physics.flu-dyn2022

Taylor dispersion in arbitrarily shaped axisymmetric channels

Ray Chang, Juan G. Santiago

Advective dispersion of solutes in long thin axisymmetric channels is important to the analysis and design of a wide range of devices, including chemical separation systems and mic…

physics.chem-ph2022★ 18 cited

Liquid Heterostructures: Generation of Liquid-Liquid Interfaces in Free-Flowing Liquid Sheets

David J. Hoffman, Hans A. Bechtel, Diego A. Huyke +3

Chemical reactions and biological processes are often governed by the structure and transport dynamics of the interface between two liquid phases. Despite their importance, our mic…

physics.chem-ph2021★ 1 cited

Microfluidic Isotachophoresis: Theory and Applications

Ashwin Ramachandran, Juan G. Santiago

Isotachophoresis (ITP) is a versatile electrophoretic technique which can be used for sample preconcentration, separation, purification, mixing, and control and acceleration of che…

physics.chem-ph2018

Frequency analysis and resonant operation for efficient capacitive deionization

Ashwin Ramachandran, Steven A. Hawks, Michael Stadermann +1

Capacitive deionization (CDI) performance metrics can vary widely with operating methods. We here develop a theory around and experimentally demonstrate a new operation for CDI tha…

physics.chem-ph2018★ 287 cited

Performance Metrics for the Objective Assessment of Capacitive Deionization Systems

Steven A. Hawks, Ashwin Ramachandran, Slawomir Porada +5

In the growing field of capacitive deionization (CDI), a number of performance metrics have emerged to describe the desalination process. Unfortunately, the separation conditions u…

physics.chem-ph2018

Thermodynamics of Ion Separation by Electrosorption

Ali Hemmatifar, Ashwin Ramachandran, Kang Liu +3

We present a simple, top-down approach for the calculation of minimum energy consumption of electrosorptive ion separation using variational form of the (Gibbs) free energy. We foc…

physics.chem-ph2017

Tailored Porous Electrode Resistance for Controlling Electrolyte Depletion and Improving Charging Response in Electrochemical Systems

James W. Palko, Ali Hemmatifar, Juan G. Santiago

The rapid charging and/or discharging of electrochemical cells can lead to localized depletion of electrolyte concentration. This depletion can significantly impact the system's ti…

physics.app-ph2017★ 29 cited

Capacitive Deionization -- defining a class of desalination technologies

P. M. Biesheuvel, M. Z. Bazant, R. D. Cusick +17

Over the past decade, capacitive deionization (CDI) has realized a surge in attention in the field of water desalination and can now be considered as an important technology class,…

q-bio.BM2017★ 1 cited

Isotachophoresis applied to chemical reactions

Charbel Eid, Juan G. Santiago

This review discusses research developments and applications of isotachophoresis (ITP) to the initiation, control, and acceleration of chemical reactions, emphasizing reactions inv…

physics.chem-ph2017

Nitrate removal from water using electrostatic regeneration of functionalized adsorbent

James W. Palko, Diego I. Oyarzun, Byunghang Ha +2

Nitrate is an important pollutant in drinking water worldwide, and a number of methods exist for the removal of nitrate from water including ion exchange and reverse osmosis. Howev…

physics.flu-dyn2015

Sensitivity analysis and study of the mixing uniformity of a microfluidic mixer

Benjamin Ivorra, Juana López Redondo, Ángel M. Ramos +1

We consider a microfluidic mixer based on hydrodynamic focusing, which is used to initiate the folding process of individual proteins. The folding process is initiated by quickly d…