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20152022
most citedPerformance Metrics for the Objective Assessment of Capacitive Deionization Systems

287 citations · 336 across the 10 of their papers we have counts for

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physics.chem-ph2022★ 18 cited

Liquid Heterostructures: Generation of Liquid-Liquid Interfaces in Free-Flowing Liquid Sheets

David J. Hoffman, Hans A. Bechtel, Diego A. Huyke +3

Chemical reactions and biological processes are often governed by the structure and transport dynamics of the interface between two liquid phases. Despite their importance, our mic…

physics.chem-ph2021★ 1 cited

Microfluidic Isotachophoresis: Theory and Applications

Ashwin Ramachandran, Juan G. Santiago

Isotachophoresis (ITP) is a versatile electrophoretic technique which can be used for sample preconcentration, separation, purification, mixing, and control and acceleration of che…

physics.chem-ph2018

Frequency analysis and resonant operation for efficient capacitive deionization

Ashwin Ramachandran, Steven A. Hawks, Michael Stadermann +1

Capacitive deionization (CDI) performance metrics can vary widely with operating methods. We here develop a theory around and experimentally demonstrate a new operation for CDI tha…

physics.chem-ph2018★ 287 cited

Performance Metrics for the Objective Assessment of Capacitive Deionization Systems

Steven A. Hawks, Ashwin Ramachandran, Slawomir Porada +5

In the growing field of capacitive deionization (CDI), a number of performance metrics have emerged to describe the desalination process. Unfortunately, the separation conditions u…

physics.chem-ph2018

Thermodynamics of Ion Separation by Electrosorption

Ali Hemmatifar, Ashwin Ramachandran, Kang Liu +3

We present a simple, top-down approach for the calculation of minimum energy consumption of electrosorptive ion separation using variational form of the (Gibbs) free energy. We foc…

physics.chem-ph2017

Tailored Porous Electrode Resistance for Controlling Electrolyte Depletion and Improving Charging Response in Electrochemical Systems

James W. Palko, Ali Hemmatifar, Juan G. Santiago

The rapid charging and/or discharging of electrochemical cells can lead to localized depletion of electrolyte concentration. This depletion can significantly impact the system's ti…

physics.chem-ph2017

Nitrate removal from water using electrostatic regeneration of functionalized adsorbent

James W. Palko, Diego I. Oyarzun, Byunghang Ha +2

Nitrate is an important pollutant in drinking water worldwide, and a number of methods exist for the removal of nitrate from water including ion exchange and reverse osmosis. Howev…