257 citations · 1k across the 9 of their papers we have counts for
9 papers
Compressibility anomalies in stretched water and their interplay with density anomalies
Vincent Holten, Chen Qiu, Emmanuel Guillerm +4
Water keeps puzzling scientists because of its numerous properties which behave oppositely to usual liquids: for instance, water expands upon cooling, and liquid water is denser th…
Comment on "Unraveling the 'Pressure Effect' in Nucleation"
Vincent Holten, J. Hrubý, M. E. H. van Dongen +1
In a 2008 Letter, Wedekind et al. discussed the influence of an inert carrier gas on the vapor-liquid nucleation rate. They found an additional "pressure-volume work" that is perfo…
Behavior of Supercooled Aqueous Solutions Stemming from Hidden Liquid-Liquid Transition in Water
John W. Biddle, Vincent Holten, Mikhail A. Anisimov
A popular hypothesis that explains the anomalies of supercooled water is the existence of a metastable liquid-liquid transition hidden below the line of homogeneous nucleation. If…
Equation of state for supercooled water at pressures up to 400 MPa
Vincent Holten, Jan V. Sengers, Mikhail A. Anisimov
An equation of state is presented for the thermodynamic properties of cold and supercooled water. It is valid for temperatures from the homogeneous ice nucleation temperature up to…
Two-state thermodynamics of the ST2 model for supercooled water
Vincent Holten, Jeremy C. Palmer, Peter H. Poole +2
Thermodynamic properties of the ST2 model for supercooled liquid water exhibit anomalies similar to those observed in real water. A possible explanation of these anomalies is the e…
Nature of the anomalies in the supercooled liquid state of the mW model of water
Vincent Holten, David T. Limmer, Valeria Molinero +1
The thermodynamic properties of the supercooled liquid state of the mW model of water show anomalous behavior. Like in real water, the heat capacity and compressibility sharply inc…
Thermal Conductivity of Supercooled Water
John W. Biddle, Vincent Holten, Jan V. Sengers +1
The heat capacity of supercooled water, measured down to -37 °C, shows an anomalous increase as temperature decreases. The thermal diffusivity, i. e., the ratio of the thermal cond…
Entropy-driven liquid-liquid separation in supercooled water
V. Holten, M. A. Anisimov
Twenty years ago Poole et al. (Nature 360, 324, 1992) suggested that the anomalous properties of supercooled water may be caused by a critical point that terminates a line of liqui…
Thermodynamics of supercooled water
V. Holten, C. E. Bertrand, M. A. Anisimov +1
We review the available experimental information on the thermodynamic properties of supercooled ordinary and heavy water and demonstrate the possibility of modeling these thermodyn…