Equation of state for supercooled water at pressures up to 400 MPa
arXiv:1403.6777 · doi:10.1063/1.4895593
Abstract
An equation of state is presented for the thermodynamic properties of cold and supercooled water. It is valid for temperatures from the homogeneous ice nucleation temperature up to 300 K and for pressures up to 400 MPa, and can be extrapolated up to 1000 MPa. The equation of state is compared with experimental data for the density, expansion coefficient, isothermal compressibility, speed of sound, and heat capacity. Estimates for the accuracy of the equation are given. The melting curve of ice I is calculated from the phase-equilibrium condition between the proposed equation and an existing equation of state for ice I.
23 pages, 30 figures. Updated after peer review; now includes a section on the vapor pressure of supercooled water. Includes ancillary material (C++ and MATLAB code, tables with property data)
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