Long-range mid-infrared energy transfer mediated by hyperbolic phonon polaritons
arXiv:2603.06184 · doi:10.1021/acs.nanolett.6c01042
Abstract
We provide a framework to theoretically describe long-range energy transfer in single and twisted two-dimensional hyperbolic slabs. We demonstrate that phonon polaritons (PhPs, quantum superpositions of photons and lattice vibrations in polar dielectrics) can mediate and enhance room-temperature energy transfer at ranges far exceeding those of conventional mid-infrared (MIR) platforms, and with extreme directionality. This is because the dipole-dipole interaction potential energy diverges along the asymptotes of the real-space hyperbolic opening angle. Our findings allow us to extend classical and quantum interactions between dipoles, typically strictly confined to the near-field, beyond several free-space MIR wavelengths. We use -MoO as a representative material, but this mechanism is not limited to the MIR: it is general to anisotropic media across the whole electromagnetic spectrum.
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