Direction-Dependent Conduction Polarity in Altermagnetic CrSb

Abstract

CrSb has recently gained immense attention as an altermagnetic candidate. This work reports on the experimental observation of direction-dependent conduction polarity (DDCP) in altermagnetic CrSb through Hall and Seebeck thermopower measurements. Conduction is dominated by holes along the c-axis and by electrons in the ab-plane of the hexagonal crystal of CrSb. Density functional theory (DFT) calculations indicate that DDCP in CrSb arises from a multicarrier mechanism, where electrons and holes living in distinct bands dominate conduction along different crystallographic directions. Furthermore, DFT predicts that DDCP exists within a narrow energy window near the Fermi level and is sensitive to small doping levels. This prediction is experimentally validated by the loss of DDCP in hole-doped Cr${}_{0.98}$V${}_{0.02}$Sb. These findings highlight the potential for tunable electronic behavior in CrSb, offering promising avenues for applications in devices that require both p-type and n-type functionalities within a single material.

18 pages, 6 main figures, 10 SI figures, 1 main table, 2 SI tables