Synthesis and physical properties of LaNiO${}_2$ crystals

Abstract

Infinite-layer (IL) nickelates are an emerging family of superconductors whose similarities and differences to cuprate superconductors are under intense debate. To date, the IL phase of nickelates can only be reached via topotactic oxygen reduction of the perovskite phase, using H${}_2$ gas or reducing agents such as CaH${}_2$. While the topotactic reduction method has been widely employed on thin film and polycrystalline powder samples, the reduction of La${}_{1-x}$Ca${}_x$NiO${}_3$ single-crystals with lateral dimensions up to 150 $\mu$m was achieved only recently, using an indirect contact method with CaH${}_2$. Here we report the topotactic transformation of much larger LaNiO${}_3$ crystals with lateral dimensions of more than one millimeter, via direct contact with CaH${}_2$. We characterize the crystalline, magnetic, and electronic properties of the obtained IL LaNiO${}_2$ crystals by powder and single-crystal x-ray diffraction (XRD), magnetometry, electrical transport, and x-ray photoelectron spectroscopy (XPS) measurements. The amount of incorporated topotactic hydrogen due to the reduction process is determined by a gas extraction method. In addition, we investigate the evolution of the lattice parameters under hydrostatic pressure up to 12 GPa, using high-resolution synchrotron XRD. Furthermore, we provide a direct comparison of several physical properties of the LaNiO${}_2$ crystals to their powder and thin film counterparts.

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Cited by in corpus (11)

• Synthesis of thin film infinite-layer nickelates by atomic hydrogen reduction: clarifying the role of the capping layer
• Topotactic-hydrogen forms chains in $AB$O${}_2$ nickelate superconductors
• Superconductivity in the parent infinite-layer nickelate NdNiO${}_2$
• Phase formation in hole- and electron-doped rare-earth nickelate single crystals
• Topotactically induced oxygen vacancy order in nickelate single crystals
• Investigation of spin excitations and charge order in bulk crystals of the infinite-layer nickelate LaNiO${}_2$
• Spin-glass state in nickelate superconductors
• Lattice dynamics of the infinite-layer nickelate LaNiO${}_2$
• Floating zone growth at high oxygen pressures in Ruddlesden-Popper bilayer nickelate Y${}_y$Sr${}_{3-y}$Ni${}_{2-x}$Al${}_x$O${}_{7-\delta }$
• Surfaces and interfaces of infinite-layer nickelates studied by dynamical mean-field theory
• Direct Evidence of Metal-Ligand Redox in Li-ion Battery Positive Electrodes