Highly sensitive spin-flop transition in antiferromagnetic van-der Waals material MPS3 (M = Ni and Mn)

Abstract

Recent developments in two-dimensional (2D) magnetism have motivated the search for novel van-der Waals (vdWs) magnetic materials to explore new magnetic phenomenon in the 2D limit. Metal thiophosphates, MPX3, is a class of magnetic vdWs materials with antiferromagnetic (AFM) ordering persisting down to the atomically thin limit. The magnetism in this material family has been found to be highly dependent on the choice of transition metal M. In this work, we have synthesized the intermediate compounds Ni1-xMnxPS3 (0 < x < 1) and investigated their magnetic properties. Our study reveals that the variation of Ni and Mn content in Ni1-xMnxPS3 can efficiently tune the spin-flop transition, likely due to the modulation of the magnetic anisotropy. Such effective tunning offers a promising candidate to engineer 2D magnetism for future device applications.

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Cited by in corpus (22)

• Controlling magnetic exchange and anisotropy by non-magnetic ligand substitution in layered MPX3 (M = Ni, Mn; X = S, Se)
• Limited ferromagnetic interactions in monolayers of MPS${}_3$ (M=Mn, Ni)
• The magnetic dynamics of NiPS${}_3$
• Evidence of Ferroelectricity in an Antiferromagnetic Vanadium Trichloride Monolayer
• The spin-flop transition in the quasi two dimensional antiferromagnet MnPS3 detected via thermally generated magnon transport
• Giant spin Nernst effect in a two-dimensional antiferromagnet due to magnetoelastic coupling-induced gaps and interband transitions between magnon-like bands
• Understanding and tuning magnetism in layered Ising-type antiferromagnet FePSe3 for potential 2D magnet
• Magnetic anisotropy and low-energy spin dynamics in the van der Waals compounds Mn${}_2$P${}_2$S${}_6$ and MnNiP${}_2$S${}_6$
• Large Negative Magnetoresistance in Antiferromagnetic Gd2Se3
• Evolution of magnetic phase in two dimensional van der Waals Mn${}_{1-x}$Ni${}_x$PS${}_3$ single crystals
• Tailoring spin waves in 2D transition metal phosphorus trichalcogenides via atomic-layer substitution
• Field-induced spin polarization in lightly Cr-substituted layered antiferromagnet NiPS3
• Spin model for the Honeycomb $\mathrm{NiP}{\mathrm{S}}_3$
• Evolution of the spin dynamics in the van der Waals system $M_{\text{2}}$P${}_{\text{2}}$S${}_{\text{6}}$ (${\mathbf{M}}_{\text{2}}$ = Mn${}_{\text{2}}$, MnNi, Ni${}_{\text{2}}$) series probed by electron spin resonance spectroscopy
• Generation of Pure Spin Current with Insulating Antiferromagnetic Materials
• Quantum Fluctuations in the van der Walls material $\mathrm{NiP}{\mathrm{S}}_3$
• Revealing the Electronic Structure of van der Waals Antiferromagnetic NiPS${}_3$ through Synchrotron-Based $\mu$-ARPES and Alkali Metal Dosing
• Mechanical resonant sensing of spin texture dynamics in a two-dimensional antiferromagnet
• Unconventional magnon transport in antiferromagnet NiPS${}_3$ induced by an anisotropic spin-flop transition
• Probing the band structure of the strongly correlated antiferromagnet NiPS3 across its phase transition
• Ultrafast Dynamics of Spin-Orbit Entangled Excitons Coupled to Magnetic Ordering in van der Waals Antiferromagnet NiPS3
• Stabilization of zigzag order in NiPS${}_3$ via positive biquadratic interaction