Evaluation and mitigation of trace ${}^{210}$Pb contamination on copper surfaces

Abstract

Clean materials are required to construct and operate many low-background physics experiments. High-purity copper has found broad use because of its physical properties and availability. In this paper, we describe methods to assay and mitigate ${}^{210}$Pb contamination on copper surfaces, such as from exposure to environmental radon or coming from bulk impurities. We evaluated the efficacy of wet etching on commercial samples and observed that ${}^{210}$Po contamination from the copper bulk does not readily pass into solution. During the etch, the polonium appears to trap at the copper-etchant boundary, such that it is effectively concentrated at the copper surface. We observed a different behavior for ${}^{210}$Pb; high-sensitivity measurements of the alpha emissivity versus time indicate the lowest level of ${}^{210}$Pb contamination ever reported for a commercial copper surface: $0\pm 12$ nBq/cm${}^2$ (1$\sigma$). Additionally, we have demonstrated the effectiveness of mitigating trace ${}^{210}$Pb and ${}^{210}$Po surface backgrounds using custom, high-purity electroplating techniques. These approaches were evaluated utilizing assays performed with an XIA UltraLo-1800 alpha spectrometer.

Published in Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment Volume 967, 1 July 2020, 163870

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Cited by in corpus (7)

• Copper electroplating for background suppression in the NEWS-G experiment
• AlphaCAMM, a Micromegas-based camera for high-sensitivity screening of alpha surface contamination
• Characterization of the background spectrum in DAMIC at SNOLAB
• Exploration of Methods to Remove Implanted ${}^{210}$Pb and ${}^{210}$Po Contamination from Silicon Surfaces
• Characterization of XIA UltraLo-1800 Response to Measuring Charged Samples
• Removal of radon progeny from delicate surfaces
• Radiopurity screening of materials for rare event searches by neutron activation at the TRIGA reactor of Pavia