Ionic Tuning of Cobaltites at the Nanoscale

Abstract

Control of materials through custom design of ionic distributions represents a powerful new approach to develop future technologies ranging from spintronic logic and memory devices to energy storage. Perovskites have shown particular promise for ionic devices due to their high ion mobility and sensitivity to chemical stoichiometry. In this work, we demonstrate a solid-state approach to control of ionic distributions in (La,Sr)CoO${}_3$ thin films. Depositing a Gd capping layer on the perovskite film, oxygen is controllably extracted from the structure, up-to 0.5 O/u.c. throughout the entire 36 nm thickness. Commensurate with the oxygen extraction, the Co valence state and saturation magnetization show a smooth continuous variation. In contrast, magnetoresistance measurements show no-change in the magnetic anisotropy and a rapid increase in the resistivity over the same range of oxygen stoichiometry. These results suggest significant phase separation, with metallic ferromagnetic regions and oxygen-deficient, insulating, non-ferromagnetic regions, forming percolated networks. Indeed, X-ray diffraction identifies oxygen-vacancy ordering, including transformation to a brownmillerite crystal structure. The unexpected transformation to the brownmillerite phase at ambient temperature is further confirmed by high-resolution scanning transmission electron microscopy which shows significant structural - and correspondingly chemical - phase separation. This work demonstrates room-temperature ionic control of magnetism, electrical resistivity, and crystalline structure in a 36 nm thick film, presenting new opportunities for ionic devices that leverage multiple material functionalities.

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• Electrically Enhanced Exchange Bias via Solid State Magneto-Ionics
• Interfacial-Redox-Induced Tuning of Superconductivity in YBa${}_2$Cu${}_3$O${}_{7-\delta }$
• Reversible Thermal Strain Control of Oxygen Vacancy Ordering in an Epitaxial La${}_{0.5}$Sr${}_{0.5}$CoO${}_{3-\delta }$ Film
• Band gap and pseudocapacitance of Gd${}_2$O${}_3$ doped with Ni${}_{0.5}$Zn${}_{0.5}$Fe${}_2$O${}_4$
• Soft X-ray Absorption Spectroscopy and Magnetic Circular Dichroism as Operando Probes of Complex Oxide Electrolyte Gate Transistors
• Dynamic nanoscale spatial heterogeneity in a perovskite to brownmillerite topotactic phase transformation