Finite-time fluctuation theorem for diffusion-influenced surface reactions on spherical and Janus catalytic particles

Abstract

A finite-time fluctuation theorem for the diffusion-influenced surface reaction A <=> B is investigated for spherical and Janus catalytic particles. The finite-time rates and thermodynamic force are analytically calculated by solving diffusion equations with the special boundary conditions of the finite-time fluctuation theorem. Theory is compared with numerical simulations carried out with two different methods: a random walk algorithm and multiparticle collision dynamics.

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Cited by in corpus (4)

• Thermodynamics and statistical mechanics of chemically-powered synthetic nanomotors
• Single particle motion and collective dynamics in Janus motor systems
• Microreversibility, fluctuations, and nonlinear transport in transistors
• Counting statistics and microreversibility in stochastic models of transistors