Idiosyncratic Approach to Visualize Degradation of Black Phosphorus

Abstract

Black Phosphorus (BP) is an excellent material for post graphene era due to its layer dependent band gap, high mobility and high Ion/Ioff. However, its poor stability in ambient poses a great challenge in its practical and long-term usage. Optical visualization of oxidized BP is the key and foremost step for its successful passivation from the ambience. Here, we have done a systematic study of the oxidation of BP and developed a technique to optically identify the oxidation of BP using Liquid Crystal (LC). Interestingly we found that rapid oxidation of thin layers of BP makes them disappear and can be envisaged by using the alignment of LC. The molecular dynamics simulations also proved the preferential alignment of LC on oxidized BP. We believe that this simple technique will be effective in passivation efforts of BP and will enable it for exploitation of its properties in the field of electronics.

References in corpus (8)

• Black phosphorus field-effect transistors
• Isolation and characterization of few-layer black phosphorus
• Effective Passivation of Exfoliated Black Phosphorus Transistors against Ambient Degradation
• Covalent Functionalization and Passivation of Exfoliated Black Phosphorus via Aryl Diazonium Chemistry
• Oxygen defects in phosphorene
• Toward Air-Stable Multilayer Phosphorene Thin-Films and Transistors
• Black phosphorus as a new broadband saturable absorber for infrared passively Q-switched fiber lasers
• Phosphorus oxide gate dielectric for black phosphorus field effect transistors

Cited by in corpus (1)

• Oxidation kinetics and non-Marcusian charge transfer in dimensionally confined semiconductors