Mode-Coupling Theory of the Glass Transition: A Primer
arXiv:1806.01369 · doi:10.3389/fphy.2018.00097
Abstract
Understanding the physics of glass formation remains one of the major unsolved challenges of condensed matter science. As a material solidifies into a glass, it exhibits a spectacular slowdown of the dynamics upon cooling or compression, but at the same time undergoes only minute structural changes. Among the numerous theories put forward to rationalize this complex behavior, Mode-Coupling Theory (MCT) stands out as the only framework that provides a fully first-principles-based description of glass phenomenology. This review outlines the key physical ingredients of MCT, its predictions, successes, and failures, as well as recent improvements of the theory. We also discuss the extension and application of MCT to the emerging field of non-equilibrium active soft matter
References in corpus (30)
- Theoretical perspective on the glass transition and amorphous materials
- The role of local structure in dynamical arrest
- Probing the equilibrium dynamics of colloidal hard spheres above the mode-coupling glass transition
- Inhomogeneous Mode-Coupling Theory and Growing Dynamic Length in Supercooled Liquids
- Growing length and time scales in glass forming liquids
- Dynamic heterogeneity in amorphous materials
- A mode coupling theory for Brownian particles in homogeneous steady shear flow
- Glassy dynamics of athermal self-propelled particles: Computer simulations and a nonequilibrium microscopic theory
- Active and Nonlinear Microrheology in Dense Colloidal Suspensions
- Hopping and the Stokes-Einstein relation breakdown in simple glass formers
- Structural relaxation of polydisperse hard spheres: comparison of the mode-coupling theory to a Langevin dynamics simulation
- Increasing the density melts ultrasoft colloidal glasses
- Glass Transition in Confined Geometry
- How active forces influence nonequilibrium glass transitions
- Cooperativity Beyond Caging: Generalized Mode Coupling Theory
- Mode-Coupling Theory for Active Brownian Particles
- Glass transition of hard spheres in high dimensions
- The role of structure and entropy in determining differences in dynamics for glass formers with different interaction potentials
- Glass Transition for Driven Granular Fluids
- Nonequilibrium mode-coupling theory for dense active systems of self-propelled particles
- A New Theory of Dynamic Arrest in Colloidal Mixtures
- Multiple reentrant glass transitions in confined hard-sphere glasses
- Fluids in Extreme Confinement
- Structural and conformational dynamics of supercooled polymer melts: Insights from first-principles theory and simulations
- Static triplet correlations in glass-forming liquids: A molecular dynamics study
- The Glass Transition in Driven Granular Fluids: A Mode-Coupling Approach
- Glassy Dynamics of Brownian Particles with Velocity-Dependent Friction
- Nonequilibrium Glass Transition in Mixtures of Active-Passive Particles
- Dynamics and rheology of active glasses
- Random First Order Theory concepts in Biology and Condensed Matter physics
Cited by in corpus (72)
- Classical dynamical density functional theory: from fundamentals to applications
- Active glasses
- Power functional theory for many-body dynamics
- Understanding, predicting, and tuning the fragility of vitrimeric polymers
- Noether's Theorem in Statistical Mechanics
- Projection operators in statistical mechanics: a pedagogical approach
- Experimental evidence of a crossover between cooperative relaxation and liquid growth dynamics
- Soft Metamaterials: Adaptation and Intelligence
- Translational and rotational dynamics of a self-propelled Janus probe in crowded environments
- Mechanical disorder of sticky-sphere glasses. I. Effect of attractive interactions
- Out-of-equilibrium dynamical equations of infinite-dimensional particle systems. I. The isotropic case
- Perspective: How to overcome dynamical density functional theory
- Cage Length Controls the Non-Monotonic Dynamics of Active Glassy Matter
- Thermodynamic-Dynamic Interrelations in Glass-Forming Polymer Fluids
- Noether-Constrained Correlations in Equilibrium Liquids
- Active Glassy Dynamics is Unaffected by the Microscopic Details of Self-Propulsion
- Many-body correlations are non-negligible in both fragile and strong glassformers
- Generalized mode-coupling theory of the glass transition. I. Numerical results for Percus-Yevick hard spheres
- The glass transition in molecules, colloids and grains: universality and specificity
- Combined Description of Pressure-Volume-Temperature and Dielectric Relaxation of Several Polymeric and Low-Molecular-Weight Organic Glass-Formers using 'SL-TS2' Mean-Field Approach
- Active microrheology of a bulk metallic glass
- Mode-coupling theory of lattice dynamics for classical and quantum crystals
- Generalized mode-coupling theory of the glass transition. II. Analytical scaling laws
- Multi-component generalized mode-coupling theory: Predicting dynamics from structure in glassy mixtures
- Waiting-time dependent non-equilibrium phase diagram of simple glass- and gel-forming liquids
- Mode-coupling theory for mixtures of athermal self-propelled particles
- Understanding probability and irreversibility in the Mori-Zwanzig projection operator formalism
- From sub-aging to hyper-aging in structural glasses
- Phase separation and dynamical arrest of protein solutions dominated by short-range attractions
- Generalized Mode-Coupling Theory for Mixtures of Brownian Particles
- Connecting real glasses to mean-field models
- Dynamical Susceptibilities Near Ideal Glass Transitions
- Mode-coupling theory of the glass transition for colloidal liquids in slit geometry
- Rheological regimes in agitated granular media under shear
- Glassy dynamics of a binary Voronoi fluid: A mode-coupling analysis
- Dynamical properties of densely packed confined hard-sphere fluids
- Glassy dynamics from generalized mode-coupling theory: existence and uniqueness of solutions for hierarchically coupled integro-differential equations
- Unveiling the anatomy of mode-coupling theory
- A deep learning approach to the measurement of long-lived memory kernels from Generalised Langevin Dynamics
- Scaling equations for mode-coupling theories with multiple decay channels
- Glassy dynamics of sticky hard spheres beyond the mode-coupling regime
- Modeling non-linear dielectric susceptibilities of supercooled molecular liquids
- An energy-landscape-based crossover temperature in glass-forming liquids
- Time-resolved thermal lens spectroscopy of glassy dynamics in supercooled liquids: theory and experiments
- Dynamic properties of quasi-confined colloidal hard-sphere liquids near the glass transition
- Gauge invariance and hyperforce correlation theory for equilibrium fluid mixtures
- Computer Simulations and Mode-Coupling Theory of Glass-Forming Confined Hard-Sphere Fluids
- Tagged-particle motion of Percus-Yevick hard spheres from first principles
- Unifying the Concepts of Scattering and Structure Factor in Ordered and Disordered Samples
- Non-equilibrium Onsager-Machlup theory
- Nonequilibrium mixture dynamics: A model for mobilities and its consequences
- Automated characterization of spatial and dynamical heterogeneity in supercooled liquids via implementation of Machine Learning
- A self-consistent current response theory of jamming and vibrational modes in low-temperature amorphous solids
- Not-so-glass-like Caging and Fluctuations of an Active Matter Model
- Glass transition in colloidal monolayers controlled by light-induced caging
- Mobility-induced kinetic effects in multicomponent mixtures
- Mode-coupling theory of the glass transition for a liquid in a periodic potential
- Nonlinear Langevin functionals for a driven probe
- General Two-Parameter Model of Alpha-Relaxation in Glasses
- Pair correlation function based on Voronoi topology
- Modeling the Dielectric Relaxation in Semicrystalline Polymers -- Understanding the Role of the Interphase between the Amorphous and Crystalline Domains
- Replica Field Theory for a Generalized Franz--Parisi Potential of Inhomogeneous Glassy Systems: New Closure and the Associated Self-Consistent Equation
- Tagged-particle motion in quasi-confined colloidal hard-sphere liquids
- Does mesoscopic elasticity control viscous slowing down in glassforming liquids?
- Time-Varying Energy Landscapes and Temperature paths: Dynamic Transition Rates in locally Ultrametric Complex Systems
- Controlling the Glass Transition through Active Fluctuating Interactions
- Efficient spectra from atomistic simulation: a generalized master equation study of the air-water interface
- Theory of the -Relaxation Beyond Mode-Coupling Theory: A Microscopic Treatment
- Ergodicity in glass relaxation
- Model dielectric functions for fluctuation potential calculations in electron gas: a critical assessment
- Analytical treatment of the structure and thermodynamics of the square-well fluid
- Probing Glass Formation in Perylene Derivatives via Atomic Scale Simulations and Bayesian Regression