Formation and Fractionation of CO (carbon monoxide) in diffuse clouds observed at optical and radio wavelengths
arXiv:1611.03783 · doi:10.3847/1538-4357/835/2/138
Abstract
We modelled \HH\ and CO formation incorporating the fractionation and selective photodissociation affecting CO when \AV\ $\la2$mag. UV absorption measurements typically have N(\cotw)/N(\coth) that are reproduced with the standard UV radiation and little density dependence at n(H) $\approx32-1024\pccc$: Densities n(H) $\la256\pccc$ avoid overproducing CO. Sightlines observed in mm-wave absorption and a few in UV show enhanced \coth\ by factors of 2-4 and are explained by higher n(H) $\ga256\pccc$ and/or weaker radiation. The most difficult observations to understand are UV absorptions having N(\cotw)/N(\coth) 100 and N(CO)$\ga10^{15}\pcc$. Plots of \WCO\ vs. N(CO) show that \WCO\ remains linearly proportional to N(CO) even at high opacity owing to sub-thermal excitation. \cotw\ and \coth\ have nearly the same curve of growth so their ratios of column density/integrated intensity are comparable even when different from the isotopic abundance ratio. For n(H)$\ga128\pccc$, plots of \WCO\ vs N(CH) are insensitive to n(H), and \WCO/N(CO)$\approx1\Kkms/(10^{15}~{\rm CO}\pcc)$: This compensates for small CO/\HH\ to make \WCO\ more readily detectable. Rapid increases of N(CO) with n(H), N(H) and N(\HH) often render the CO bright, ie a small CO-\HH\ conversion factor. For n(H) $\la64\pccc$ CO enters the regime of truly weak excitation where \WCO n(H)N(CO). \WCO\ is a strong function of the average \HH\ fraction and models with \WCO=1\Kkms\ fall in the narrow range \mfH2\=0.65-0.8, or \mfH2\=0.4-0.5 at \WCO\=0.1\Kkms. The insensitivity of easily-detected CO emission to gas with small \mfH2\ implies that even deep CO surveys using broad beams may not discover substantially more emission.
arXiv commentAccepted for The Astrophysical Journal
References in corpus (41)
- Interstellar Dust Grains
- The Milky Way in Molecular Clouds: A New Complete CO Survey
- The Neutral Atomic Phases of the ISM in the Galaxy
- Structure of Stationary Photodissociation Fronts
- The Dark Molecular Gas
- The photodissociation and chemistry of CO isotopologues: applications to interstellar clouds and circumstellar disks
- Large-Scale Structure of the Molecular Gas in Taurus Revealed by High Linear Dynamic Range Spectral Line Mapping
- Planck Early Results: All sky temperature and dust optical depth from Planck and IRAS: Constraints on the "dark gas" in our galaxy
- A FUSE Survey of Interstellar Molecular Hydrogen in Translucent Clouds
- Ultraviolet Survey of CO and H_2 in Diffuse Molecular Clouds: The Reflection of Two Photochemistry Regimes in Abundance Relationships
- Herschel Survey of Galactic OH+, H2O+, and H3O+: Probing the Molecular Hydrogen Fraction and Cosmic-Ray Ionization Rate
- HI-to-H2 Transitions and H I Column Densities in Galaxy Star-Forming Regions
- The Chemistry of Interstellar OH+, H2O+, and H3O+: Inferring the Cosmic Ray Ionization Rates from Observations of Molecular Ions
- Abundances and Behavior of 12CO, 13CO, and C2 in Translucent Sight Lines
- Direct Measurement of the Ratio of Carbon Monoxide to Molecular Hydrogen in the Diffuse Interstellar Medium
- Interstellar Hydrides
- Isotopic fractionation of carbon, deuterium and nitrogen : a full chemical study
- Observations of H3+ in the Diffuse Interstellar Medium
- H2 formation and excitation in the diffuse interstellar medium
- The CO luminosity and CO-H2 conversion factor of diffuse ISM: does CO emission trace dense molecular gas?
- Optically thick HI dominant in the local interstellar medium; an alternative interpretation to "dark gas"
- Formation, fractionation and excitation of carbon monoxide in diffuse clouds
- Carbon Fractionation in PDRs
- Comparative Chemistry of Diffuse Clouds IV: CH
- The CO/CO ratio in turbulent molecular clouds
- Gas-phase recombination, grain neutralization and cosmic-ray ionization in diffuse gas
- Hubble Space Telescope Survey of Interstellar ^12CO/^13CO in the Solar Neighborhood
- Cold and warm atomic gas around the Perseus molecular cloud I: Basic Properties
- Imaging diffuse clouds: Bright and dark gas mapped in CO
- Atomic and Molecular Carbon as a Tracer of Translucent Clouds
- Diffuse Molecular Cloud Densities from UV Measurements of CO Absorption
- How well does CO emission measure the H mass of MCs?
- Chemical Analysis of a Diffuse Cloud along a Line of Sight Toward W51: Molecular Fraction and Cosmic-Ray Ionization Rate
- Ultraviolet Detection of Interstellar 12C17O and the CO Isotopomeric Ratios toward X Persei
- Time-dependent H2 formation and protonation
- Low energy H+CO scattering revisited: CO rotational excitation with new potential surfaces
- HD/H2 as a probe of the roles of gas, dust, light, metallicity and cosmic rays in promoting the growth of molecular hydrogen in the diffuse interstellar medium
- Reanalysis of Copernicus Measurements on Interstellar Carbon Monoxide
- The detectability of mm-wave molecular rotational transitions
- An unbiased deep search for small-area molecular structures
- A CO J=1-0 Survey of common optical/uv absorption sightlines
Cited by in corpus (13)
- The first steps of Interstellar Phosphorus Chemistry
- C18O, 13CO, and 12CO abundances and excitation temperatures in the Orion B molecular cloud: An analysis of the precision achievable when modeling spectral line within the Local Thermodynamic Equilibrium approximation
- Chemical complexity in local diffuse and translucent clouds: ubiquitous l-C3H and CH3CN, a detection of HC3N and an upper limit on the abundance of CH2CN
- Dense gas formation in the Musca filament due to the dissipation of a supersonic converging flow
- Standing in the shadow of dark gas: ALMA observations of absorption from dark CO in the molecular DNM of Chamaeleon
- Molecular Gas and Dark Neutral Medium in the Outskirts of Chamaeleon
- Molecular hydrogen and its proxies HCO and CO in the diffuse interstellar medium
- CO+ as a probe of the origin of CO in diffuse interstellar clouds
- Carina's Pillars of Destruction: the view from ALMA
- The Dark Neutral Medium is (Mostly) Molecular Hydrogen
- CO emission and CO hotspots in diffuse molecular gas
- CO-CHANGES I: IRAM 30m CO Observations of Molecular Gas in the Sombrero Galaxy
- What did the seahorse swallow? APEX 170 GHz observations of the chemical conditions in the Seahorse infrared dark cloud