Understanding the fundamental connection between electronic correlation and decoherence

Abstract

We introduce a theory that exposes the fundamental and previously overlooked connection between the correlation among electrons and the degree of quantum coherence of electronic states in matter. For arbitrary states, the effects only decouple when the electronic dynamics induced by the nuclear bath is pure-dephasing in nature such that $[H^S,H^{SB}]=0$, where $H^S$ is the electronic Hamiltonian and $H^{SB}$ is the electron-nuclear coupling. We quantitatively illustrate this connection via exact simulations of a Hubbard-Holstein molecule using the Hierarchical Equations of Motion that show that increasing the degree of electronic interactions can enhance or suppress the rate of electronic coherence loss.

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Cited by in corpus (3)

• Probing the energy conversion pathways between light, carriers and lattice in real time with attosecond core-level spectroscopy
• Lessons on electronic decoherence in molecules from exact modeling
• Quantifying fermionic decoherence in many-body systems