Vibrational quenching of the electronic ground state in ThO in cold collisions with He
arXiv:1310.7279 · doi:10.1103/PhysRevA.90.032703
Abstract
We measure the ratio of the momentum-transfer to the vibrational quenching cross section for the X (), , state of molecular thorium monoxide (ThO) in collisions with atomic He between 800 mK and 2.4 K. We observe indirect evidence for ThO--He van der Waals' complex formation, which has been predicted by theory. We determine the 3-body recombination rate constant at 2.4 K, and establish that the binding energy E 4 K.