Timescales in creep and yielding of attractive gels

Abstract

The stress-induced yielding scenario of colloidal gels is investigated under rough boundary conditions by means of rheometry coupled to local velocity measurements. Under an applied shear stress, the fluidization of gels made of attractive carbon black particles suspended in a mineral oil is shown to involve a previously unreported shear rate response $\dot{\gamma }(t)$ characterized by two well-defined and separated timescales ${\tau }_c$ and ${\tau }_f$. First $\dot{\gamma }(t)$ decreases as a weak power law strongly reminiscent of the primary creep observed in numerous crystalline and amorphous solids, coined the "Andrade creep." We show that the bulk deformation remains homogeneous at the micron scale, which demonstrates that if plastic events take place or if any shear transformation zone exists, such phenomena occur at a smaller scale. As a key result of this paper, the duration ${\tau }_c$ of this creep regime decreases as a power law of the viscous stress, defined as the difference between the applied stress and the yield stress with an exponent ranging between 2 and 3 depending on the gel concentration. The end of this first regime is marked by a jump of the shear rate by several orders of magnitude, while the gel slowly slides as a solid block experiencing strong wall slip at both walls, despite rough boundary conditions. Finally, a second sudden increase of the shear rate is concomitant to the full fluidization of the material which ends up being homogeneously sheared. The corresponding fluidization time ${\tau }_f$ robustly follows an exponential decay with the applied shear stress as already reported for smooth boundary conditions. Finally, we highlight a few features that are common to attractive colloidal gels and to solid materials by discussing our results in the framework of theoretical approaches of solid rupture (kinetic, fiber bundle, and transient network models).

Main: 18 pages, 15 figures - Supplemental: 5 pages, 6 figures - Accepted for publication in Soft Matter (Nov. 2013)

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