Shear-induced reinforcement in boehmite gels: a rheo-X-ray-scattering study

Abstract

Boehmite, an aluminum oxide hydroxide $\gamma$-AlO(OH), is broadly used in the form of particulate dispersions in industrial applications, e.g., for the fabrication of ceramics and catalyst supports or as a binder for extrusion processes. Under acidic conditions, colloidal boehmite dispersions at rest form gels, i.e., space-spanning percolated networks that behave as soft solids at rest, and yet yield and flow like liquids under large enough deformations. Like many other colloidal gels, the solid-like properties of boehmite gels at rest are very sensitive to their previous mechanical history. Our recent work [Sudreau et al., J. Rheol. 66, 91-104 (2022), and Phys. Rev. Material 6, L042601 (2022)] has revealed such \textit{memory effects}, where the shear experienced prior to flow cessation drives the elasticity of boehmite gels: while gels formed following application of a shear rate ${\dot{\gamma }}_{\mathrm{p}}$ larger than a critical value ${\dot{\gamma }}_{\mathrm{c}}$ are insensitive to shear history, gels formed after application of ${\dot{\gamma }}_{\mathrm{p}}<{\dot{\gamma }}_{\mathrm{c}}$ display reinforced viscoelastic properties and non-negligible residual stresses. Here, we provide a microstructural scenario for these striking observations by coupling rheometry and small-angle X-ray scattering. Time-resolved measurements for ${\dot{\gamma }}_{\mathrm{p}}<{\dot{\gamma }}_{\mathrm{c}}$ show that scattering patterns develop an anisotropic shape that persists upon flow cessation, whereas gels exposed to ${\dot{\gamma }}_{\mathrm{p}}>{\dot{\gamma }}_{\mathrm{c}}$ display isotropic scattering patterns upon flow cessation. Moreover, as the shear rate applied prior to flow cessation is decreased below ${\dot{\gamma }}_{\mathrm{c}}$, the level of anisotropy frozen in the sample microstructure grows similarly to the viscoelastic properties, thus providing a direct link between mechanical reinforcement and flow-induced microstructural anisotropy.

13 pages, 10 figures

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