Giant magnetocaloric effect in magnetically frustrated EuHo$_2$O$_4$ and EuDy$_2$O$_4$ compounds

A. Midya; N. Khan; D. Bhoi; P. Mandal

doi:10.1063/1.4754849

paper

Giant magnetocaloric effect in magnetically frustrated EuHo $_{2}$ O $_{4}$ and EuDy $_{2}$ O $_{4}$ compounds

arXiv:1209.2513 · doi:10.1063/1.4754849

Abstract

We have investigated the magnetic and magnetocaloric properties of EuHo $_{2}$ O $_{4}$ and EuDy $_{2}$ O $_{4}$ by magnetization and heat capacity measurements down to 2 K. These compounds undergo a field-induced antiferromagnetic to ferromagnetic transition and exhibit a huge entropy change. For a field change of 0-8 T, the maximum magnetic entropy and adiabatic temperature changes are 30 (25) J kg $^{- 1}$ K $^{- 1}$ and 12.7 (16) K, respectively and the corresponding value of refrigerant capacity is 540 (415) J kg $^{- 1}$ for EuHo $_{2}$ O $_{4}$ (EuDy $_{2}$ O $_{4}$ ). These magnetocaloric parameters also remain large down to lowest temperature measured and are even larger than that for some of the potential magnetic refrigerants reported in the same temperature range for a moderate field change. Moreover, these materials are highly insulating and exhibit no thermal and field hysteresis, fulfilling the necessary conditions for a good magnetic refrigerant in the low-temperature region.

Giant magnetocaloric effect in magnetically frustrated EuHo $_{2}$ O $_{4}$ and EuDy $_{2}$ O $_{4}$ compounds

Abstract

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Giant magnetocaloric effect in magnetically frustrated EuHo2​O4​ and EuDy2​O4​ compounds

Abstract

References in corpus (3)

Cited by in corpus (13)

Giant magnetocaloric effect in magnetically frustrated EuHo $_{2}$ O $_{4}$ and EuDy $_{2}$ O $_{4}$ compounds