paper

Magnetic and magnetocaloric properties of quasi-one-dimensional Ising spin chain CoVO

arXiv:1509.01690 · doi:10.1063/1.4945395

Abstract

We have investigated the magnetic and magnetocaloric properties of antiferromagnetic Ising spin chain CoVO by magnetization and heat capacity measurements. Both monoclinic -CoVO and triclinic -CoVO exhibit field-induced metamagnetic transition from antiferromagnetic to ferromagnetic state via an intermediate ferrimagnetic state with 1/3 magnetization plateau. Due to this field-induced metamagnetic transition, these systems show large conventional as well as inverse magnetocaloric effects. In -CoVO, we observe field-induced complex magnetic phases and multiple magnetization plateaux at low temperature when the field is applied along axis. Several critical temperatures and fields have been identified from the temperature and field dependence of magnetization, magnetic entropy change and heat capacity to construct the - phase diagram. As compared to -CoVO, -CoVO displays a relatively simple magnetic phase diagram. Due to the large magnetic entropy change and adiabatic temperature change at low or moderate applied magnetic field, -CoVO may be considered as a magnetic refrigerant in the low-temperature region.

10 pages, 10 figures

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