Sharp transition for single polarons in the one-dimensional Su-Schrieffer-Heeger model

Abstract

We study a single polaron in the Su-Schrieffer-Heeger (SSH) model using four different techniques (three numerical and one analytical). Polarons show a smooth crossover from weak to strong coupling, as a function of the electron-phonon coupling strength $\lambda$, in all models where this coupling depends only on phonon momentum $q$. In the SSH model the coupling also depends on the electron momentum $k$; we find it has a sharp transition, at a critical coupling strength ${\lambda }_c$, between states with zero and nonzero momentum of the ground state. All other properties of the polaron are also singular at $\lambda ={\lambda }_c$, except the average number of phonons in the polaronic cloud. This result is representative of all polarons with coupling depending on $k$ and $q$, and will have important experimental consequences (eg., in ARPES and conductivity experiments).