Diffusion of a sphere in a dilute solution of polymer coils

Abstract

We calculate the short time and the long time diffusion coefficient of a spherical tracer particle in a polymer solution in the low density limit by solving the Smoluchowski equation for a two-particle system and applying a generalized Einstein relation (fluctuation dissipation theorem). The tracer particle as well as the polymer coils are idealized as hard spheres with a no-slip boundary condition for the solvent but the hydrodynamic radius of the polymer coils is allowed to be smaller than the direct-interaction radius. We take hydrodynamic interactions up to 11th order in the particle distance into account. For the limit of small polymers, the expected generalized Stokes-Einstein relation is found. The long time diffusion coefficient also roughly obeys the generalized Stokes-Einstein relation for larger polymers whereas the short time coefficient does not. We find good qualitative and quantitative agreement to experiments.

9 Pages, 6 Figures, J. Chem. Phys. (in print)

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