Tracing shocks and photodissociation in the Galactic center region
arXiv:0801.3614 · doi:10.1086/533409
Abstract
We present a systematic study of the HNCO, C18O, 13CS, and C34S emission towards 13 selected molecular clouds in the Galactic center region. The molecular emission in these positions are used as templates of the different physical and chemical processes claimed to be dominant in the circumnuclear molecular gas of galaxies. The relative abundance of HNCO shows a variation of more than a factor of 20 amo ng the observed sources. The HNCO/13CS abundance ratio is highly contrasted (up to a factor of 30) between the shielded molecular clouds mostly affected by shocks, where HNCO is released to gas-phase from grain mantles, and those pervaded by an intense UV radiation field, where HNCO is photo-dissociated and CS production favored via ion reactions. We propose the relative HNCO to CS abundance ratio as a highly contrasted diagnostic tool to distinguish between the influence of shocks and/or the radiation field in the nuclear regions of galaxies and their relation to the evolutionary state of their nuclear star formation bursts.
25 pages, 5 figures, Accepted for publication in ApJ
References in corpus (6)
- A multi-transition HCN and HCO+ study of 12 nearby active galaxies: AGN versus SB environments
- A 2 mm spectral line survey of the starburst galaxy NGC 253
- The largest oxigen bearing organic molecule repository
- Low sulfur depletion in the Horsehead PDR
- Overluminous HNC Line Emission in Arp220, NGC4418 and Mrk231 - Global IR Pumping or XDRs?
- Methanol detection in M82
Cited by in corpus (54)
- Discovery of Fulminic Acid, HCNO, in Dark Clouds
- Discovery in space of ethanolamine, the simplest phospholipid head group
- Thiols in the ISM: first detection of HC(O)SH and confirmation of CHSH
- Molecules with a peptide link in protostellar shocks: a comprehensive study of L1157
- Prebiotic precursors of the primordial RNA world in space: Detection of NHOH
- Lambda = 3 mm line survey of nearby active galaxies
- Cloud-cloud collision as drivers of the chemical complexity in Galactic Centre molecular clouds
- Multi-molecule ALMA observations towards the Seyfert 1 galaxy NGC 1097
- ALCHEMI: an ALMA Comprehensive High-resolution Extragalactic Molecular Inventory. Survey presentation and first results from the ACA array
- Phosphorus-bearing molecules in the Galactic Center
- Propargylimine in the laboratory and in space: millimetre-wave spectroscopy and first detection in the ISM
- Precursors of fatty alcohols in the ISM: Discovery of n-propanol
- Probing the chemical complexity of amines in the ISM: detection of vinylamine (CHNH) and tentative detection of ethylamine (CHNH)
- First detection of CHNCO in the ISM and search of other isocyanates towards the G+0.693-0.027 molecular cloud
- Detection of the cyanomidyl radical (HNCN): a new interstellar species with the NCN backbone
- New N-bearing species towards OH231.8+4.2: HNCO, HNCS, HCN and NO
- First detection in space of the high-energy isomer of cyanomethanimine: H2CNCN
- Amides inventory towards the G+0.693-0.027 molecular cloud
- 3 mm spectral line survey of two lines of sight toward two typical cloud complexes in the Galactic Center
- ATLASGAL --- Molecular fingerprints of a sample of massive star forming clumps
- On the abiotic origin of dimethyl sulfide: discovery of DMS in the Interstellar Medium
- Diverse nuclear star-forming activities in the heart of NGC 253 resolved with ten-pc scale ALMA images
- Discovery of thionylimide, HNSO, in space: the first N-, S- and O-bearing interstellar molecule
- Toward the limits of complexity of interstellar chemistry: Rotational spectroscopy and astronomical search for n- and i-butanal
- Structure and kinematics of shocked gas in Sgr B2: further evidence of a cloud-cloud collision from SiO emission maps
- Deuterium fractionation as a multi-phase component tracer in the Galactic Centre
- M0.20-0.033: An Expanding Molecular Shell in the Galactic Center Radio Arc
- The first detection of SiC in the interstellar medium
- Shocking Sgr B2(N1) with its own outflow: A new perspective on segregation between O- and N-bearing molecules
- Isocyanic acid (HNCO) in the Hot Molecular Core G331.512-0.103: Observations and Chemical Modelling
- The chemical footprint of AGN feedback in the outflowing circumnuclear disk of NGC 1068
- Sulfur-bearing species in molecular clouds
- Understanding if molecular ratios can be used as diagnostics of AGN and starburst activity: The case of NGC 1068
- Reconstructing the shock history in the CMZ of NGC 253 with ALCHEMI
- ALMA observations of the dense and shocked gas in the nuclear region of NGC 4038 (Antennae galaxies)
- The Fossil Nuclear Outflow in the Central 30 pc of the Galactic Center
- Conformational isomerism of methyl formate: new detections of the higher-energy trans conformer and theoretical insights
- Extended HNCO, SiO, and HCN emission in 43 southern star-forming regions
- Millimetre and submillimetre spectroscopy of isobutene and its detection in the molecular cloud G+0.693
- H2CN/H2NC abundance ratio: a new potential temperature tracer for the interstellar medium
- Rotation-tunneling spectrum and astrochemical modeling of dimethylamine, CHNHCH, and searches for it in space
- The salty emission of the intermediate-mass AGB star OH 30.1 -0.7
- On the effects of UV photons/X-rays on the chemistry of the Sgr B2 cloud
- The GUAPOS project. VI: the chemical inventory of shocked gas
- Tracing the chemical footprint of shocks in AGN-host and starburst galaxies with ALMA multi-line molecular studies
- Advancing spectroscopic understanding of HOCS: Laboratory investigations and astronomical implications
- A detection of sulfur-bearing cyclic hydrocarbons in space
- A high-resolution spectroscopic analysis of aminoacrylonitrile and an interstellar search towards G+0.693
- Chemical templates of the Central Molecular Zone. Shock and protostellar object signatures under Galactic Center conditions
- Surveying the Whirlpool at Arcseconds with NOEMA (SWAN) II: Survey design and observations
- Expanding the CHO Isomeric Interstellar Inventory: Discovery of Lactaldehyde and Methoxyacetaldehyde in G+0.693-0.027
- The Chemistry and Kinematics of Two Molecular Clouds near Sagittarius A*
- Precursors of the RNA-world in space: Detection of ()-1,2-ethenediol in the interstellar medium, a key intermediate in sugar formation
- Synthesis and Spectroscopic Characterization of Interstellar Candidate Ethynyl Thiocyanate: HCCSCN