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cond-mat.stat-mech2024★ 20 cited
Test of the formal basis of Arrhenius law with heat capacities
Denis Michel
The exponential factor of Arrhenius satisfactorily quantifies the energetic restriction of chemical reactions but is still awaiting a rigorous basis. Assuming that the Arrhenius eq…
cond-mat.stat-mech2014★ 2 cited
New treatments of density fluctuations and recurrence times for re-estimating Zermelo's paradox
Denis Michel
What is the probability that all the gas in a box accumulates in the same half of this box? Though amusing, this question underlies the fundamental problem of density fluctuations…