5 papers
Topological control of local electroneutrality in confined electrolytes
Marcelo Lozada-Cassou
Topology governs finite-size violations of local electroneutrality in confined electrolytes. Within Poisson-Boltzmann theory, we show that this topological control gives rise to a…
Local Electroneutrality Violation as a Universal Constraint in Confined Electrolytes
M. Lozada-Cassou
We show that finite-size violations of local electroneutrality in confined electrolytes are governed by the topology of the confining domain, yielding a universal hierarchy of devi…
Topological impact of nanopore electrodes on the structure of the electrical double layer and the di erential capacitance
A. Silva-Caballero, A. Lozada-Hidalgo, M. Lozada-Cassou
The electrical double layer for three different topologies of nanopore electrodes is studied, i.e., the interior and exterior electrical double layers of planar, cylindrical and sp…
Unified Symmetry Breaking in Confined Electrolytes: Charge, Chemical Potential, and the Nonlinear Capacitance of Hollow Nanoparticles
Marcelo Lozada-Cassou
We study the nonlinear electrostatic response of electrolyte-filled, hollow charged nanoparticles, modeled as nanocapacitors with finite wall thickness and curved geometry.
Contact theorems for electrolyte-filled hollow charged nanoparticles: Non-linear osmotic pressure in confined electrolytes
Marcelo Lozada-Cassou, Sócrates AnÃbal Rivera-Cerecero
Analytical expressions for the osmotic pressure of electrolytes confined within electrolyte-filled, hollow, charged nanoparticles are studied using contact theorems for cavity nano…