Unified Symmetry Breaking in Confined Electrolytes: Charge, Chemical Potential, and the Nonlinear Capacitance of Hollow Nanoparticles
arXiv:2506.05644 · doi:10.1140/epjs/s11734-025-01932-1
Abstract
We study the nonlinear electrostatic response of electrolyte-filled, hollow charged nanoparticles, modeled as nanocapacitors with finite wall thickness and curved geometry.
arXiv comment50 pages, 9 figures, one appendix
References in corpus (4)
- Charge Fluctuation Forces Between Stiff Polyelectrolytes in Salt Solution: Pairwise Summability Re-examined
- Electroneutrality Breakdown and Specific Ion Effects in Nanoconfined Aqueous Electrolytes Observed by NMR
- Charge neutrality breakdown in confined aqueous electrolytes: theory and simulation
- Ion size effects at ionic exclusion from dielectric interfaces and slit nanopores