85 citations · 194 across the 5 of their papers we have counts for
5 papers
Stochastic Transition States: Reaction Geometry amidst Noise
Thomas Bartsch, Rigoberto Hernandez, T. Uzer
Classical transition state theory (TST) is the cornerstone of reaction rate theory. It postulates a partition of phase space into reactant and product regions, which are separated…
The Transition State in a Noisy Environment
Thomas Bartsch, Rigoberto Hernandez, T. Uzer
Transition State Theory overestimates reaction rates in solution because conventional dividing surfaces between reagents and products are crossed many times by the same reactive tr…
Chemical Reaction Dynamics within Anisotropic Solvents in Time-Dependent Fields
Eli Hershkovits, Rigoberto Hernandez
The dynamics of low-dimensional Brownian particles coupled to time-dependent driven anisotropic heavy particles (mesogens) in a uniform bath (solvent) have been described through t…
The projection of a nonlocal mechanical system onto the irreversible generalized Langevin equation, II: Numerical simulations
Marc Vogt, Rigoberto Hernandez
The irreversible generalized Langevin equation (iGLE) contains a nonstationary friction kernel that in certain limits reduces to the GLE with space-dependent friction. For more gen…
Dissipating the Langevin equation in the presence of an external stochastic potential
Jeremy M. Moix, Rigoberto Hernandez
In the Langevin formalism, the delicate balance maintained between the fluctuations in the system and their corresponding dissipation may be upset by the presence of a secondary, s…