257 citations · 1.8k across the 39 of their papers we have counts for
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Modeling Fluid Polyamorphism Through a Maximum-Valence Approach
Nikolay A. Shumovskyi, Thomas J. Longo, Sergey V. Buldyrev +1
We suggest a simple model to describe polyamorphism in single-component fluids using a maximum-valence approach. The model contains three types of interactions: i) atoms attract ea…
Structure Factor of a Phase Separating Binary Mixture with Natural and Forceful Interconversion of Species
Thomas J. Longo, Nikolay A. Shumovskyi, Salim M. Asadov +2
Using a modified Cahn-Hilliard-Cook theory for spinodal decomposition in a binary mixture that exhibits both diffusion and interconversion dynamics, we derive the time-dependent st…
Interconversion-controlled liquid-liquid phase separation in a molecular chiral model
Betul Uralcan, Thomas J. Longo, Mikhail A. Anisimov +2
Liquid-liquid phase separation of liquids exhibiting interconversion between alternative states has been proposed as an underlying mechanism for fluid polyamorphism, and may be of…
Minimal microscopic model for liquid polyamorphism and water-like anomalies
Frédéric Caupin, Mikhaïl A. Anisimov
Liquid polyamorphism is the intriguing possibility for a single component substance to exist in multiple liquid phases. We propose a minimal model for this phenomenon. Starting wit…
Phase Transitions Affected by Natural and Forceful Molecular Interconversion
Thomas J. Longo, Mikhail A. Anisimov
If a binary liquid mixture, composed of two alternative species with equal amounts, is quenched from a high temperature to a low temperature, below the critical point of demixing,…
Phase Amplification in Spinodal Decomposition of Immiscible Fluids with Interconversion of Species
Nikolay A. Shumovskyi, Thomas J. Longo, Sergey V. Buldyrev +1
A fluid composed of two molecular species may undergo phase segregation via spinodal decomposition. However, if the two molecular species can interconvert, e.g. change their chiral…