257 citations · 1.8k across the 39 of their papers we have counts for
8 papers · 1 filter
Two-state thermodynamics of the ST2 model for supercooled water
Vincent Holten, Jeremy C. Palmer, Peter H. Poole +2
Thermodynamic properties of the ST2 model for supercooled liquid water exhibit anomalies similar to those observed in real water. A possible explanation of these anomalies is the e…
Phase behavior and mesoscale solubilization in aqueous solutions of hydrotropes
Deepa Subramanian, Mikhail A. Anisimov
Hydrotropes are amphiphilic molecules that are too small to spontaneously form equilibrium structures in aqueous solutions, but form dynamic, noncovalent assemblies, referred to as…
Mesoscale phenomena in solutions of 3-methylpyridine, heavy water, and an antagonistic salt
Jan Leys, Deepa Subramanian, Eva Rodezno +2
We have investigated controversial issues regarding the mesoscale behavior of 3-methylpyridine (3MP), heavy water, and sodium tetraphenylborate (NaBPh4) solutions by combining resu…
Thermodynamic anomalies and structural fluctuations in aqueous solutions of tertiary butyl alcohol
Deepa Subramanian, Jeffery B. Klauda, Jan Leys +1
In this work, we discuss the connection between the anomalies of the thermodynamic properties, experimentally observed in tertiary butyl alcohol (TBA) and water solutions, and the…
Fifty Years of Breakthrough Discoveries in Fluid Criticality
Mikhail A. Anisimov
Fifty years ago two scientists, who celebrate their 80th birthdays in 2011, Alexander V. Voronel and Johannes V. Sengers performed breakthrough experiments that challenged the comm…
Universality versus nonuniversality in asymmetric fluid criticality
M. A. Anisimov
Critical phenomena in real fluids demonstrate a combination of universal features caused by the divergence of long-range fluctuations of density and nonuniversal (system-dependent)…