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cond-mat.mtrl-sci2026
Selective Octahedral Accommodation of Cr and Weak Magnetic Connectivity in the Sugilite Analogue KNaCrLiSiO
Yuya Haraguchi, Taishu Aoki, Daisuke Nishio-Hamane +1
We report the synthesis of the Cr analogue of sugilite, KNaCrLiSiO, in the milarite-type framework. Rietveld refinement of a composition-conserving antisi…
cond-mat.mtrl-sci2026
Ilmenite-Type CaIrO via Topochemical Ion Exchange: Stacking Faults and Low-Temperature Magnetic Anomaly
Haruki Kira, Yuya Haraguchi, Wataru Yokoshima +2
We report the synthesis of an ilmenite-type polymorph of CaIrO distinct from the known post-perovskite and perovskite phases, via low-temperature topochemical Ca/2Na…
cond-mat.mtrl-sci2024
High-temperature magnetic anomaly via suppression of antisite disorder through synthesis route modification in a Kitaev candidate CuIrO
Yuya Haraguchi, Daisuke Nishio-Hamane, Akira Matsuo +2
By incorporating inert KCl into the NaIrO + 2CuCl CuIrO + 2NaCl topochemical reaction, we significantly reduced the synthesis temperature of CuIrO fro…