9 papers
Tetrahedrally ferromagnetic correlations and a glassy-freezing anomaly in the breathing pyrochlore magnet with partial -site disorder
Yuya Haraguchi, Masahiro Kitamura, Masaki Gen +6
We investigate the chromium breathing pyrochlore sulfide , a chromium-based thiospinel, by synchrotron x-ray and neutron powder diffraction, dc magnetization,…
Selective Octahedral Accommodation of Cr and Weak Magnetic Connectivity in the Sugilite Analogue KNaCrLiSiO
Yuya Haraguchi, Taishu Aoki, Daisuke Nishio-Hamane +1
We report the synthesis of the Cr analogue of sugilite, KNaCrLiSiO, in the milarite-type framework. Rietveld refinement of a composition-conserving antisi…
Evolution of crystal field and intraionic interactions in the ilmenite IrO ( = Mg, Zn, Cd) and hyperhoneycomb -ZnIrO
Yuya Haraguchi, Hiroko Aruga Katori, Kenji Ishii +1
Spin-orbit Mott insulators with the electron configuration are promising platforms for the Kitaev spin liquid, yet fine-tuning of their crystal structures is essential t…
Ilmenite-Type CaIrO via Topochemical Ion Exchange: Stacking Faults and Low-Temperature Magnetic Anomaly
Haruki Kira, Yuya Haraguchi, Wataru Yokoshima +2
We report the synthesis of an ilmenite-type polymorph of CaIrO distinct from the known post-perovskite and perovskite phases, via low-temperature topochemical Ca/2Na…
Crystalline water intercalation into the Kitaev honeycomb cobaltate NaCoTeO
Masaaki Ito, Yuya Haraguchi, Teruki Motohashi +4
We herein report the successful intercalation of water molecules into the layered honeycomb lattice of NaCoTeO, a Kitaev-candidate compound, to obtain the hydrated phas…
Frustrated Diamond Lattice Antiferromagnet CoTiO with a Vacancy-ordered Spinel Structure Synthesized via a Topochemical Reaction
Rio Kumeda, Yuya Haraguchi, Daisuke Nishio-Hamane +3
Metastable CoTiO was synthesized through a topochemical reaction using LiCoTiO as the precursor, resulting in a vacancy-ordered spinel structure. Crystal st…