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physics.chem-ph2026
Thermodynamics Reconstructed from Information Theory:An Axiomatic Framework via Information-Volume Constraints and Path-Space KL Divergence
Tatsuaki Tsuruyama
We develop an axiomatic reconstruction of thermodynamics based entirely on two primitive components: a description of what aspects of a system are observed and a reference measure…
physics.chem-ph2024
Large Deviation Theory Approach to Fluctuation Theorems and Landauer's Principle through Heat Redefinition
Tatsuaki Tsuruyama
Large deviation theory (LDT) provides a mathematical framework to quantify the probabilities of rare events in stochastic systems. In this study, we applied LDT to model a chemical…