X-ray photoemission characterization of La_{0.67}(Ca_{x}Sr_{1-x})_{0.33}MnO_{3} films
arXiv:cond-mat/9901189 · doi:10.1063/1.369995
Abstract
The Curie temperature and x-ray photoemission spectra of thin films of La_{0.67}(Ca_{x}Sr_{1-x})_{0.33}MnO_{3} (LCSMO) have been studied as a function of the Ca/Sr ratio. The films were grown by off-axis cosputtering from individual targets of La_{0.67}Ca_{0.33}MnO_{3} (LCMO) and La_{0.67}Sr_{0.33}MnO_{3} (LSMO) onto (100) oriented NdGaO_{3} substrates. The films grow with a (100) orientation, with no other orientations observed by x-ray diffraction. For the alloy mixtures, the Curie temperature, T_C, varies slowly as the Ca/Sr is decreased, remaining 300 K, while for the LCMO and LSMO films T_C is 260 and 330 K, respectively. The Mn-O valence structure is composed of two dominant peaks, whose positions undergo a change as the Ca fraction is decreased. The core lines behave as linear combinations of lines from pure LCMO and LSMO.
3 pages, 5 eps figures. To be published in Journal of Applied Physics (Proceedings of MMM'98)