paper

Ionic Reactions in Two Dimensions with Disorder

arXiv:cond-mat/9805076 · doi:10.1103/PhysRevE.58.1487

Abstract

We analyze the dynamics of the ion-dipole pairing reaction in the two-dimensional Coulomb gas in the presence of disorder. Sufficiently singular disorder forces the critical temperature of the Kosterlitz-Thouless-Berezinskii fixed point to be non-universal. This disorder leads to anomalous ion pairing kinetics with a continuously variable decay exponent. Sufficiently strong disorder eliminates the transition altogether. For ions that are chemically reactive, anomalous kinetics with a continuously variable decay exponent also occurs in the high-temperature regime. The Coulomb interaction inhibits reactant segregation, and so the ionic reaction behaves like the nonionic reaction.

To appear in Phys. Rev. E. 7 pages, 4 figures

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