Evidence for local lattice distortions in giant magnetocapacitive CdCr2S4

Abstract

Raman scattering experiments on CdCr2S4 single crystals show pronounced anomalies in intensity and frequency of optical phonon modes with an onset temperature T*=130 K that coincides with the regime of giant magnetocapacitive effects. A loss of inversion symmetry and Cr off-centering are deduced from the observation of longitudinal optical and formerly infrared active modes for T<T_c=84 K. The intensity anomalies are attributed to the enhanced electronic polarizability of displacements that modulate the Cr-S distance and respective hybridization. Photo doping leads to an annihilation of the symmetry reduction. Our scenario of multiferroic effects is based on the near degeneracy of polar and nonpolar modes and the additional low energy scale due to hybridization.

4 pages, 6 figures

References in corpus (6)

• First-principles study of spontaneous polarization in multiferroic BiFeO${}_3$
• Recent progress in first-principles studies of magnetoelectric multiferroics
• Coupling between magnetic ordering and structural instabilities in perovskite biferroics: A first-principles study
• Relaxation dynamics and colossal magnetocapacitive effect in CdCr2S4
• Colossal Electroresistance and Colossal Magnetoresistance in Spinel Multiferroic CdCr2S4
• Polar phonons and spin-phonon coupling in HgCr2S4 and CdCr2S4

Cited by in corpus (4)

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• Magnetoelectric and Raman spectroscopic studies of single-crystalline MnCr2O4
• On the complexity of spinels: Magnetic, electronic, and polar ground states