Influence of magnetic interaction between impurity and impurity-liberated spins on the magnetism in the doped Haldane chain compounds PbNi${}_{2-x${A}${}_x$V${}_2$O${}_8$ (A = Mg, Co)

Abstract

A comprehensive study of impurity-induced magnetism in nonmagnetically (Mg${}^{2+}$) and magnetically (Co${}^{2+}$) doped PbNi${}_2$V${}_2$O${}_8$ compounds is given, using both macroscopic dc susceptibility and local-probe electron spin resonance (ESR) techniques. Magnetic coupling between impurity-liberated spins is estimated from a linewidth of low-temperature ESR signal in Mg-doped samples. In addition, in the case of magnetic cobalt dopants the impurity-host magnetic exchange is evaluated from the Co-induced contribution to the linewidth in the paramagnetic phase. The experimentally observed severe broadening of the ESR lines in the magnetically doped compounds with respect to nonmagnetic doping is attributed to a rapid spin-lattice relaxation of the Co${}^{2+}$ ions, which results in a bottleneck-type of temperature dependence of the induced linewidth. The exchange parameters obtained from the ESR analysis offer a satisfactory explanation of the observed low-temperature magnetization in doped samples.

arXiv comment8 pages, 6 figures

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Cited by in corpus (1)

• Magnetic versus nonmagnetic doping effects on the magnetic ordering in the Haldane chain compound PbNi2V2O8