Interpretation of Light Scattering Spectra in Terms of Particle Displacements

Abstract

Quasi-elastic light scattering spectroscopy of dilute solutions of diffusing mesoscopic probe particles is regularly used to examine the dynamics of the fluid through which the probe particles are moving. For probes in a simple liquid, the light scattering spectrum is a simple exponential; the field correlation function $g_P^{(1)}(q,\tau )$ of the scattering particles is related to their mean-square displacements $\overline{X^2}\equiv <(\Delta x(\tau ){)}^2>$ during $\tau$ via $g^{(1)}(q,\tau )=\exp (-1/2q^2\overline{X^2})$. However, historical demonstrations of this expression refer only to ideal Brownian particles in simple liquids, and show that if the form is correct then it is also true that $g^{(1)}(q,\tau )=\exp (-\Gamma \tau )$, a pure exponential in $\tau$. In general, $g_P^{(1)}(q,\tau )$ is not a single exponential in time. $g_P^{(1)}(q,\tau )$ reflects not only the mean-square particle displacements but also all higher-order mean displacement moments $\overline{X^{2n}}$. A correct general form for $g^{(1)}(q,\tau )$, replacing the generally-incorrect $\exp (-1/2q^2\overline{X^2})$, is obtained. A simple experimental diagnostic determining when the field correlation function gives the mean-square displacements is identified, namely $g^{(1)}(q,\tau )$ reveals $\overline{X^2}$ if $g^{(1)}(q,\tau )$ is exponential in $\tau$.

Now 19 pages, no figures, accepted by Journal of Chemical Physics Revision: Add New Section V Spectrum of a Bidisperse System giving a concrete example of issues raised, and did minor rewrites