Magnetic behaviour of quasi-one-dimensional oxides, Ca$_3$Co$_(1+x)$Mn$_{1-x}$O$_6$

S. Rayaprol; Kausik Sengupta; E. V. Sampathkumaran

doi:10.1016/S0038-1098(03)00618-5

paper

Magnetic behaviour of quasi-one-dimensional oxides, Ca $_{3}$ Co $_{(} 1 + x)$ Mn $_{1 - x}$ O $_{6}$

arXiv:cond-mat/0306426 · doi:10.1016/S0038-1098(03)00618-5

Abstract

The results of ac and dc magnetization and heat capacity measurements on the oxides, Ca $_{3}$ Co $_{1 + x}$ Mn $_{1 - x}$ O $_{6}$ , forming in a K $_{4}$ CdCl $_{6}$ -derived rhombohedral quasi-one-dimensional crystal structure, are reported. As far as Ca $_{3}$ Co $_{2}$ O $_{6}$ is concerned, the results reveal truly complex nature of the two magnetic transitions, identified to set in at 24 and 12 K in the previous literature. However, partial replacement of Co by Mn apparently results in a long magnetic ordering of an antiferromagnetic type (below 13 and 18 K for x= 0.0 and 0.25 respectively), instead of spin-glass freezing in spite of the fact that there is Co-Mn disorder; in addition, interestingly there are hysteretic spin reorientation effects as revealed by isothermal magnetization behavior.

Magnetic behaviour of quasi-one-dimensional oxides, Ca $_{3}$ Co $_{(} 1 + x)$ Mn $_{1 - x}$ O $_{6}$

Abstract

References in corpus (5)

Cited by in corpus (24)

Magnetic behaviour of quasi-one-dimensional oxides, Ca3​Co(​1+x)Mn1−x​O6​

Abstract

References in corpus (5)

Cited by in corpus (24)

Magnetic behaviour of quasi-one-dimensional oxides, Ca $_{3}$ Co $_{(} 1 + x)$ Mn $_{1 - x}$ O $_{6}$