Free Energy Functional for Nonequilibrium Systems: An Exactly Solvable Case
arXiv:cond-mat/0105110 · doi:10.1103/PhysRevLett.87.150601
Abstract
We consider the steady state of an open system in which there is a flux of matter between two reservoirs at different chemical potentials. For a large system of size , the probability of any macroscopic density profile is ; thus generalizes to nonequilibrium systems the notion of free energy density for equilibrium systems. Our exact expression for is a nonlocal functional of , which yields the macroscopically long range correlations in the nonequilibrium steady state previously predicted by fluctuating hydrodynamics and observed experimentally.
4 pages, RevTeX. Changes: correct minor errors, add reference, minor rewriting requested by editors and referee
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