On the origin of biquadratic exchange in spin 1 chains
arXiv:cond-mat/0006068 · doi:10.1007/s100510070242
Abstract
One dimensional spin 1 systems may have a rich phase diagram including Haldane gap and dimerized phases if the usually very small biquadratic exchange becomes significant. We show that this unlikely condition may be fulfilled in electron systems with quasi-degenerate orbitals. This mechanism may have been experimentally realized in the spin 1 chain LiVGeO. The implications for the exploration of the physics and quantum chemistry of spin 1 chains are discussed.
4 pages, 4 Postscript figures. To appear in Eur. Phys. J B as a Rapid Note
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