paper

Evaluation of configurational entropy of a model liquid from computer simulations

arXiv:cond-mat/0005225 · doi:10.1088/0953-8984/12/29/323

Abstract

Computer simulations have been employed in recent years to evaluate the configurational entropy changes in model glass-forming liquids. We consider two methods, both of which involve the calculation of the `intra-basin' entropy as a means for obtaining the configurational entropy. The first method involves the evaluation of the intra-basin entropy from the vibrational frequencies of inherent structures, by making a harmonic approximation of the local potential energy topography. The second method employs simulations that confine the liquid within a localized region of configuration space by the imposition of constraints; apart from the choice of the constraints, no further assumptions are made. We compare the configurational entropies estimated for a model liquid (binary mixture of particles interacting {\it via} the Lennard-Jones potential) for a range of temperatures, at fixed density.

10 pages, 5 figures, Proceedings of "Unifying Concepts in Glass Physics" Trieste 1999 (to appear in J. Phys. Cond. Mat.)

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