A Novel Decoupling Method for Investigating Distinct Domain Evolution in Ferroelectric Film

Abstract

Conventional polarization characterization techniques provide only the averaged response of ferroelectric films, limiting the investigation of domain-dependent reliability mechanisms in HfO2-based ferroelectrics. In this work, a new domain decoupling method is proposed to separately analyze ferroelectric domains with distinct switching behaviors. A three-domain model consisting of upward non-switchable domains, downward non-switchable domains, and switchable domains (Pd) is first introduced to describe heterogeneous domain populations during electrical cycling. By combining complementary switching-current measurements, the responses of different domain populations can be selectively extracted and reconstructed. The proposed method enables quantitative tracking of individual domain populations during cycling. As a demonstration, the method is further applied to analyze the time-dependent evolution of domain populations after electrical cycling. This approach provides a new route for investigating imprint, fatigue, and other reliability-related phenomena in ferroelectric devices.