Observation of Room-temperature Charge Density Wave Correlations via Coherent Phonon Spectroscopy in Sn-doped Kagome Superconductor CsV${}_3$Sb${}_5$

Abstract

In this work, we perform ultrafast time-resolved reflectivity measurements to track the evolution of charge density wave (CDW) correlations in Sn-doped Kagome superconductor CsV${}_3$Sb${}_{5-x}$Sn${}_x$. By extracting the coherent phonon spectrum, we evidence robust signatures of CDW correlations at temperature and doping ranges far beyond the phase boundary of long-range CDW order. Remarkably, we unveil short-range CDW correlations survive up to room temperature in $x=0.32$ Sn-doped CsV${}_3$Sb${}_5$, supported by synchrotron X-ray diffraction measurements. We point out the introduction of quenched disorder by Sn doping can pin the CDW and form static short-range CDW, which can explain the observed persistent CDW signatures. Our results thus corroborate the ubiquity and robustness of CDW correlations in Sn-doped CsV${}_3$Sb${}_5$ and provide new insights on the role of disorders on the CDW correlations in AV${}_3$Sb${}_5$ family.

Accepted to Physical Review B