Chiral crossroads in $\mathrm{H}{\mathrm{o}}_3\mathrm{Sc}{\mathrm{O}}_6$: a tale of frustration in maple leaf lattice

Abstract

Motivated by the recent observation of a uniform vector chirality (UVC) magnetic order in the maple-leaf lattice (MLL) realization $\mathrm{H}{\mathrm{o}}_3\mathrm{Sc}{\mathrm{O}}_6$ via powder neutron scattering experiments, we investigate the classical antiferromagnetic Heisenberg model on the maple-leaf lattice. The MLL features three symmetry-inequivalent nearest-neighbor couplings, $J_d$, $J_t$, and $J_h$. Previous studies, primarily focused on the case where $J_t=J_h$, identified a staggered vector chirality (SVC) order. Extending beyond this limit, we demonstrate that the SVC order remains stable across a broad parameter regime. However, we also find that the UVC order cannot emerge from the nearest-neighbor model alone. By introducing a further-neighbor antiferromagnetic interaction, $J_x$, we demonstrate that even a weak $J_x$ can cause a first-order phase transition from SVC to UVC order. Using linear spin wave theory, we compute the dynamical spin structure factor, revealing distinct signatures for SVC and UVC orders that can be probed through inelastic neutron scattering experiments. Additionally, we calculate the specific heat, which exhibits qualitative agreement with the experimental data for $\mathrm{H}{\mathrm{o}}_3\mathrm{Sc}{\mathrm{O}}_6$. Our findings provide a minimal framework for understanding $\mathrm{H}{\mathrm{o}}_3\mathrm{Sc}{\mathrm{O}}_6$ and related MLL systems, like $\mathrm{MgM}{\mathrm{n}}_3{\mathrm{O}}_7.3{\mathrm{H}}_2\mathrm{O}$, suggesting avenues for further experimental and theoretical investigations.

8 pages, 5 figures

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Cited by in corpus (4)

• Symmetry breaking and competing valence bond states in the star lattice Heisenberg antiferromagnet
• Unconventional orders in the maple-leaf ferro-antiferromagnetic Heisenberg model
• Spin excitation of the Heisenberg antiferromagnet with frustration: from the bounce-lattice antiferromagnet through the maple-leaf-lattice antiferromagnet to the exact-dimer system
• Crystallography-driven molecularization of a two-dimensional spin-$3/2$ magnet