Crystal melting influenced by particle cooperativity of the liquid
arXiv:2410.20434 · doi:10.1103/PhysRevB.110.134110
Abstract
Recently, a universal relation between the thermal expansion coefficient of glasses , their glass-transition temperature Tg, and the so-called fragility index m of the corresponding supercooled liquid state was found to be valid for more than 200 glass formers, namely [P. Lunkenheimer et al., Nat. Phys. 19, 694 (2023)]. Here we show that this could also have far-reaching consequences for our understanding of crystal melting. Namely, when considering the empirically founded 2/3-rule, stating that the ratio of Tg and the melting temperature Tm is about 2/3 for almost all materials, for crystals a similar relation, , should apply. Indeed, we find that the available experimental data are well consistent with such a relation. This implies that the melting of a crystal into an ordinary (non-supercooled) liquid is influenced by the fragility, a property quantifying the non-Arrhenius dynamics in the supercooled-liquid state of the material. We argue that this can be explained by a significant enhancement of the "ideal" (non-cooperative) melting temperature arising from the cooperativity of the particle motion in the liquid state above Tm. Therefore, a reassessment of the currently widely accepted microscopic understanding of crystal melting, still founded on the general ideas that lead to the time-honored Lindemann melting criterion, may be necessary.
arXiv comment9 pages, 3 figures + 6 pages Supplemental Material
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