Temperature development of glassy alpha-relaxation dynamics determined by broadband dielectric spectroscopy
arXiv:1004.5137 · doi:10.1103/PhysRevE.81.051504
Abstract
We present the temperature dependence of alpha-relaxation times of 13 glass formers determined from broadband dielectric spectroscopy, also including data from aging measurements. The data sets partly cover relaxation-time ranges of up to 16 decades enabling a critical test of the validity of model predictions. For this purpose, the data are provided for electronic download. Here we employ these results to test the applicability of the Vogel-Fulcher-Tammann equation and a recently proposed new approach that was demonstrated to provide superior fits of a vast collection of viscosity data.
6 pages, 5 figures, final version with minor revisions according to referee demands. The relaxation time data published in the present work can be downloaded at http://link.aps.org/supplemental/10.1103/PhysRevE.81.051504
References in corpus (9)
- Glassy Aging Dynamics
- Broadband Dielectric Spectroscopy on Glass-Forming Propylene Carbonate
- The excess wing in the dielectric loss of glass-forming ethanol: A relaxation process
- Broadband dielectric spectroscopy on benzophenone: alpha relaxation, beta relaxation, and mode coupling theory
- - and - Relaxation Dynamics of a fragile plastic crystal
- Glassy dynamics in mono-, di-, and tri-propylene glycol: From the alpha- to the fast beta-relaxation
- Dielectric spectroscopy on aging glasses
- Dielectric spectroscopy in benzophenone: The beta relaxation and its relation to the mode-coupling Cole-Cole peak
- Broadband dielectric spectroscopy and aging of glass formers
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